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[Page 2] T W E L F T H E D I T I O N CHEMISTRY T H E C E N T R A L S C I E N C E [Page 4] Theodore L. Brown University of Illinois at Urbana-Champaign H. Eugene L E May, Jr. University of Nevada, Reno Bruce E. Bursten University of Tennessee, Knoxville Catherine J. Murphy University of Illinois at Urbana-Champaign Patrick M. Woodward The Ohio State University T W E L F T H E D I T I O N CHEMISTRY T H E C E N T R A L S C I E N C E [Page 5] Editor in Chief, Chemistry: Adam Jaworski Acquisitions Editor: Terry Haugen Marketing Manager: Erin Gardner Project Editor: Jennifer Hart Editorial Assistant: Catherine Martinez Marketing Assistant: Nicola Houston VP/Executive Director, Development: Carol Trueheart Development Editor, Text: Irene Nunes Development Editor, Art: Greg Gambino Managing Editor, Chemistry and Geosciences: Gina M. Cheselka Project Manager: Shari Toron Full-Service Project Management/Composition: Rebecca Dunn/Preparé, Inc. Senior Manufacturing and Operations Manager: Nick Sklitsis Operations Specialist: Maura Zaldivar Art Director: Mark Ong Senior Technical Art Specialist: Connie Long Art Studio: Precision Graphics Photo Research Manager: Elaine Soares Photo Researcher: Eric Schrader Senior Media Producer: Angela Bernhardt Associate Media Producer: Kristin Mayo Media Supervisor: Liz Winer Production Coordinator, Media: Shannon Kong Electrostatic Potential Maps: Richard Johnson, Chemistry Department, University of New Hampshire Cover Credit: Graphene by Dr. Jannik C. Meyer of the University of Ulm, Germany Copyright © 2012, 2009, 2006, 2003, 2000, 1997, 1994, 1991, 1988, 1985, 1981, 1977 Pearson Education, Inc., publishing as Pearson Prentice Hall. All rights reserved. Manufactured in the United States of America. This publication is protected by Copyright and permission should be obtained from the publisher prior to any prohibited reproduction, storage in a retrieval system, or transmission in any form or by any means, electronic, mechanical, photocopying, recording, or likewise. To obtain permission(s) to use material from this work, please submit a written request to Pearson Education, Inc., Permissions Department, 1900 E. Lake Ave., Glenview, IL 60025. Many of the designations used by manufacturers and sellers to distinguish their products are claimed as trademarks. Where those designations appear in this book, and the publisher was aware of a trademark claim, the designations have been printed in initial caps or all caps. Library of Congress Cataloging-in-Publication Data Chemistry: the central science / Theodore